Ignition delay time and speciation of dibutyl ether at high pressures
نویسندگان
چکیده
Abstract Dibutyl ether (DBE) is a promising biofuel due to its high cetane number (~ 100) and volumetric energy density (31.6 MJ/L). It could either be used directly in compression ignition engines or blended with other conventional renewable fuels. Oxidation pyrolysis kinetics of DBE are not well known, particularly at pressures. In this work, we have experimentally investigated the chemical three domains: (a) delay time measurements rapid machine over T = 550–650 K, P = 10, 20, 40 bar, ? = 0.5, 1; (b) shock tube T = 900–1300 K, P = 20, (c) laser-based carbon monoxide speciation during oxidation T = 1100–1400 K, P = 20 bar. Pressure time-histories measured RCM experiments exhibited unique 3-stage 4-stage behavior predominantly fuel-lean conditions. Experimental data were compared predictions two recent kinetic models DBE. Sensitivity analyses carried out identify key reactions which may caused discrepancy between simulations. was found that rate decomposition need revisited improve oxidative pyrolytic model.
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ژورنال
عنوان ژورنال: Combustion and Flame
سال: 2021
ISSN: ['1556-2921', '0010-2180']
DOI: https://doi.org/10.1016/j.combustflame.2020.09.028